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Battery electrolyte question
Disclaimer: I don't know a lot about the technical aspects of batteries, nor
do I claim to ! I have three group 27 batteries and a 3 stage charger that stays on 24/7. I'm guessing the charger does pretty well at adjusting it's rate, as I find I only need to add a very small amount (one squirt or two from a bulb) of liquid to the batteries every 6 - 8 weeks or so. I was using distilled water as recommended but it occurred to me that, at some point, the battery would have all water and no electrolyte left. I'm sure I'm flawed in my thinking here, so enlighten me. So anyway, I've taken to stoping by Sears and picking up the small containers of electrolyte (they're cheap enough) and topping off with them. Am I doing damage ? A good thing ? Makes no difference ? thanks jim bailey |
#2
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Battery electrolyte question
Jim-
All reputable flooded cell battery manufacturers will warn against adding electrolyte...only add distilled water. Regards- Charlie |
#3
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Battery electrolyte question
Bad idea. If you added quite a bit, you might actually have to fully charge
them, dump the elextrolyte out, and dilute it back down to the correct specific density. ----------------------------------------------------------- Solar Electric Discussion Forum: http://www.wind-sun.com/forum/ ----------------------------------------------------------- "Jim Bailey" wrote in message m... Disclaimer: I don't know a lot about the technical aspects of batteries, nor do I claim to ! I have three group 27 batteries and a 3 stage charger that stays on 24/7. I'm guessing the charger does pretty well at adjusting it's rate, as I find I only need to add a very small amount (one squirt or two from a bulb) of liquid to the batteries every 6 - 8 weeks or so. I was using distilled water as recommended but it occurred to me that, at some point, the battery would have all water and no electrolyte left. I'm sure I'm flawed in my thinking here, so enlighten me. So anyway, I've taken to stoping by Sears and picking up the small containers of electrolyte (they're cheap enough) and topping off with them. Am I doing damage ? A good thing ? Makes no difference ? thanks jim bailey |
#4
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Battery electrolyte question
Jim:
When a battery is overcharged it "gasses" or some say "boils" the water away. The later term is very incorrect. What happens if the battery is overcharged (and all battery chargers overcharge a little bit) is that the extra voltage above the cell voltage is breaking down the water (H20) into hydrogen and oxygen. That is the gas bubbles you see. To replace the lost water, you add water only. Do not add electrolyte, because as others have already said, you will be increasing the electrolyte concentration more than is desirable. So, ONLY ADD DISTILLED WATER. David |
#5
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Battery electrolyte question
Thanks to everyone who replied ! Great information - I get it now...
Hopefully I haven't put enough in there yet to cause damage - what would the symptoms be ? jim "djmarchand" wrote in message news Jim: When a battery is overcharged it "gasses" or some say "boils" the water away. The later term is very incorrect. What happens if the battery is overcharged (and all battery chargers overcharge a little bit) is that the extra voltage above the cell voltage is breaking down the water (H20) into hydrogen and oxygen. That is the gas bubbles you see. To replace the lost water, you add water only. Do not add electrolyte, because as others have already said, you will be increasing the electrolyte concentration more than is desirable. So, ONLY ADD DISTILLED WATER. David |
#6
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Battery electrolyte question
On Thu, 21 Aug 2003 12:06:42 GMT, "Jim Bailey"
wrote: Disclaimer: I don't know a lot about the technical aspects of batteries, nor do I claim to ! I have three group 27 batteries and a 3 stage charger that stays on 24/7. I'm guessing the charger does pretty well at adjusting it's rate, as I find I only need to add a very small amount (one squirt or two from a bulb) of liquid to the batteries every 6 - 8 weeks or so. I was using distilled water as recommended but it occurred to me that, at some point, the battery would have all water and no electrolyte left. I'm sure I'm flawed in my thinking here, so enlighten me. You never need to add acid to any battery. When a battery is charged, the H2 in the H2O is converted to hydrogen gas, which bubbles up and is exhausted out. As the electrolyte gasses, and the level drops, the acid concentration INCREASES not decreases, until we add DISTILLED WATER ONLY to the cells to control it. When someone doesn't replace the water, the concentrated acid that only covers the bottom half of the plates can now eat away the bottom of the plates it touches FAR better than the maintained battery could. So, it eats away the plates so bad it eats holes in them, that cannot be recharged. You can get a lot more out of a battery by increasing the amount of acid in them, probably DOUBLING its capacity for ONE discharge! But, the acid content in the electrolyte PROTECTS the plates from EROSION. If there's so much acid in the cell that it eats away the edges and makes holes in the plates before the cell goes "dead" from running out of acid, the concentration of Lead Sulphate in the electrolyte starts crystalizing and falling out of the intensely saturated solution. Once lead sulphate has precipitated, it cannot be recovered. Also, once the plates are "eaten away", the surface area of the total of the plates drops and IT cannot be recovered. The trick is to have just enough acid to eat away the SURFACE of the plates without eating away the CORE of the plates before we run out of acid. Running out of acid, not plates is when a battery cell goes "dead" and its voltage drops because its internal resistance goes way up without acid. The solution doesn't saturate and little lead sulphate crystalizes and falls out of suspension, so the charger can force off the lead into ions that rebond with the lead plates and we can get ALMOST back to the previously charged condition, ready to be discharged again. Every discharge cycle loses some plate surface to sulphation. Really DEEP discharges because there's too much acid in the cells allowing it REALLY loses a lot of lead and the plates shrink fast! Don't add acid unless it's to balance cells and you know what you are doing. So anyway, I've taken to stoping by Sears and picking up the small containers of electrolyte (they're cheap enough) and topping off with them. Am I doing damage ? A good thing ? Makes no difference ? Yes, you're simply ruining the batteries by loading them with acid. They'll keep discharging further into unrecoverable oblivion and if you took it apart you'd see big, unrecoverable holes eaten into the plates. Larry W4CSC Maybe we could get the power grid fixed if every politician regulating the power companies wasn't on their payrolls. |
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